GEOLOGICA CARPATHICA
, DECEMBER 2019, 70, 6, 471–482
doi: 10.2478/geoca-2019-0027
www.geologicacarpathica.com
Decompressional equilibration of the Midsund granulite
from Otrøy, Western Gneiss Region, Norway
JOHANNA HOLMBERG
1
, MICHAŁ BUKAŁA
2
, PAULINE JEANNERET
1
, IWONA KLONOWSKA
1, 2
and JAROSŁAW MAJKA
1, 2,
1
Department of Earth Sciences, Uppsala University, Villavägen 16, 752 36 Uppsala, Sweden;
jaroslaw.majka@geo.uu.se
2
Faculty of Geology, Geophysics and Environmental Protection, AGH University of Science and Technology, Mickiewicza 30,
30-059 Kraków, Poland
(Manuscript received June 10, 2019; accepted in revised form October 24, 2019)
Abstract: The Western Gneiss Region (WGR) of the Scandinavian Caledonides is an archetypal terrain for high-pressure
(HP) and ultrahigh-pressure (UHP) metamorphism. However, the vast majority of lithologies occurring there bear no,
or only limited, evidence for HP or UHP metamorphism. The studied Midsund HP granulite occurs on the island of Otrøy,
a locality known for the occurrence of the UHP eclogites and mantle-derived, garnet-bearing ultramafics. The Midsund
granulite consists of plagioclase, garnet, clinopyroxene, relict phengitic mica, biotite, rutile, quartz, amphibole, ilmenite
and titanite, among the most prominent phases. Applied thermodynamic modelling in the NCKFMMnASHT system
resulted in a pressure–temperature (P–T) pseudosection that provides an intersection of compositional isopleths of
X
Mg
(Mg/Mg+Fe) in garnet, albite in plagioclase and X
Na
(Na/Na+Ca) in clinopyroxene in the stability field of melt +
plagioclase + garnet + clinopyroxene + amphibole + ilmenite. The obtained thermodynamic model yields P–T conditions of
1.32–1.45 GPa and 875–970 °C. The relatively high P–T recorded by the Midsund granulite may be explained as an effect
of equilibration due to exhumation from HP (presumably UHP) conditions followed by a period of stagnation under HT
at lower-to-medium crustal level. The latter seems to be a more widespread phenomenon in the WGR than previously
thought and may well explain commonly calculated pressure contrasts between neighboring lithologies in the WGR and
other HP–UHP terranes worldwide.
Keywords: Scandinavian Caledonides, thermodynamic modelling, granulite facies metamorphism, decompression.
Introduction
A multitude of recent studies have shown that continental
crust can be subducted to mantle depths during collisional
orogenies (see Gilotti 2013 and references therein). This pro-
cess results in densification of the subducting continental plate
due to formation of mineral assemblages that are stable under
high- to ultrahigh-pressure (HP–UHP) conditions. Hence, both
mafic and felsic protoliths that are present in the subducting
plate should be transformed into eclogites and HP–UHP gneis-
ses that contain index minerals typical for eclogite facies con-
ditions. However, it is known from both field observations and
through petrological studies (e.g., Young & Kylander-Clark
2015) that the majority of the rock volume in HP–UHP ter-
ranes shows little to no evidence for metamorphism under
eclogite facies conditions. This phenomenon generally results
from either overstepping of metamorphic reactions (e.g., Castro
& Spear 2017) or from pervasive re-equilibration of eclogitic
assemblages during exhumation (e.g., Engvik et al. 2018).
A combination of both is also possible. Thus, the commonly
observed plagioclase-bearing mineral assemblages could either
have been effectively metastable during the peak metamor-
phism, because the kinetic barrier for the formation of jadeite
+ quartz at the expense of plagioclase has not been overcome,
or have been formed during retrogression. In turn, there
may be various reasons for the aforementioned phenomena.
The most prominent reasons include the variability in the sub-
duction and exhumation rates, availability of fluids, and the
rock bulk chemistry (e.g., Hacker et al. 2003).
Here, we report results from a granulite that was sampled
on the island of Otrøy in the Western Gneiss Region (WGR),
Scandinavian Caledonides, which is a well-known locality for
exposures of UHP eclogites and ultramafic rocks (e.g.,
Kylander- Clark et al. 2007; van Roermund 2009a, b). We demon-
strate through petrography, coupled with phase equilibrium
thermodynamic modelling, that the bulk chemical composi-
tion of the examined granulite allowed for the stabilization of
the plagioclase-bearing assemblage under relatively high pres-
sure. We suggest that the observed mineral assemblage is
an effect of decompressional equilibration during exhumation
from HP (presumably even UHP) conditions, associated with
limited partial melting. Notwithstanding the above considera-
tions, the studied Midsund granulite provides additional
evidence for a complex subduction–exhumation history
recorded by continental crust of the WGR in the Scandinavian
Cale donides.
Geological setting
The Scandinavian Caledonides (Fig. 1A) formed as a result
of Ordovician closure of the Iapetus Ocean and subsequent
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, 2019, 70, 6, 471–482
collision of Laurentia and Baltica in the late Silurian/early
Devonian (Gee 1975; Corfu et al. 2006, 2014; Gee et al. 2008,
2013). This continent–continent collisional event caused:
(1) the amalgamation and thrusting of oceanic and continental
allochthons (the Lower, Middle, Upper and Uppermost alloch-
thons) towards the east-southeastward over the autochthonous
basement (Roberts & Gee 1985; Roberts 2003); and (2) during
the final stages of orogenesis, the westward continental sub-
duction of part of the Baltica basement with segments of over-
lying allochthons beneath Laurentia that resulted in HP–UHP
metamorphism (e.g., Gee 1975; Andersen et al. 1991, 1998;
Kylander-Clark et al. 2007, 2008; Walsh et al. 2007; Gee et al.
2013; DesOrmeau et al. 2015; Gordon et al. 2016). In many
areas, thrust imbrication and later extensional deformation,
Fig. 1. A — Simplified tectonostratigraphic map of the Scandinavian Caledonides with inferred provenance of the major tectonic units
(modified after Gee et al. 2010). In red the Allochthonous Baltica basement including the Western Gneiss Region (WGR) is marked.
B — Simplified geological map of the Molde–Ålesund region belonging to the WGR that consists of allochthonous Caledonide nappes (in dark
grey) infolded into Baltica basement gneisses (in pink). The study area is outlined by the black rectangle and shown in more detail in Fig. 1C.
C — Geological map of Otrøy Island showing occurrences of peridotites and eclogites within the Proterozoic basement gneisses in the northern
part; separated from the southern allochthonous sequence, the Blåhø Nappe (modified after van Roermund et al. 2005; Carswell et al. 2006;
Spengler 2006; Hollocher et al. 2007; van Roermund 2009a; Hacker et al. 2010). The locations of sample documented and discussed in this
paper is outlined by the red star (EUREF89 NTM 74550 m E, 6977750 m N).
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including folding, resulted in the juxtaposition and tight inter-
folding of the nappes and basement rocks, particularly along
the western coast of Norway (Fig. 1A, B; Gee 1980; Krill
1980; Tucker 1986; Robinson 1995; Braathen et al. 2000;
Robinson & Hollocher 2008; Gee et al. 2010). Throughout
the Scandinavian Caledonides, the occurrence of numerous
windows in the allochthonous nappes exposes the parautoch-
thonous Baltica basement rocks (Fig. 1A; Roberts & Gee 1985;
Roberts 2003). The WGR, representing the hinterland of the
Scandinavian Caledonides, is one of those tectonic windows
and corresponds to the deepest exposed structural level (Gee
1975) and the largest exposure of parautochtonous basement
(Fig. 1B). The basement of the WGR consists mainly of
granitic, granodioritic, and tonalitic gneisses of Proterozoic
age (Fig. 1B) that were formed c. 1690–1620 Ma (Brueckner
1972; Carswell & Harvey 1985; Harvey 1985; Tucker et al.
1990; Skår 2000; Austrheim et al. 2003; Corfu et al. 2014;
DesOrmeau et al. 2015; Young 2017). The basement rocks
were subsequently: (1) overprinted by granulite-facies meta-
morphism related to the Sveconorwegian orogeny at c. 1100–
900 Ma that was associated with pluton and dyke emplacement
and local migmatization (Skår & Pedersen 2003; Røhr et al.
2004, 2013; Tucker et al. 2004; Root et al. 2005; Glodny et al.
2008; Kylander-Clark et al. 2008; Krogh et al. 2011; Corfu et
al. 2014; DesOrmeau et al. 2015); and (2) reworked during the
Caledonian orogeny (e.g., Fossen 2010). High-grade meta-
morphism, reaching HP–UHP conditions, occurred during
the final stages of the Scandian collision at c. 420 to 400 Ma
(e.g., Kylander-Clark et al. 2008; Hacker et al. 2010; Krogh et
al. 2011). This was followed by a lower-pressure (1.5–0.5 GPa),
granulite/amphibolite facies overprint at 400–385 Ma (Terry
et al. 2000; Kylander-Clark et al. 2007, 2008; Walsh et al. 2007;
Krogh et al. 2011; DesOrmeau et al. 2015; Hacker et al. 2015;
Holder et al. 2015).
The UHP rocks (eclogites and quartzofeldspathic gneisses)
crop out at three discrete areas within the WGR. These are
the southern (Nordfjord), central (Sørøyane), and northern
(Nordøyane) UHP domains (e.g., Hacker et al. 2010; Butler
et al. 2013; Smith & Godard 2013; DesOrmeau et al. 2015).
Overall, these UHP rocks show a northeasterly increase in
the peak UHP metamorphic conditions from 750 °C and
3.5 GPa in the Nordfjord UHP domain (e.g., Cuthbert et al.
2000; Young et al. 2007; Smith & Godard 2013; Des -
Ormeau et al. 2015; Butler et al. 2018) to 820–850 °C and
3.8–3.9 GPa in the Nordøyane UHP domain (Fig. 1B; e.g.,
Terry et al. 2000; Carswell et al. 2006; DesOrmeau et al.
2015). Even higher P–T estimates (850–950 °C and 5.5–
6.5 GPa) have been suggested for orthopyroxene eclogites
and garnet websterites hosted by gneisses of the northern
WGR in the Moldefjord region (including Otrøy island of
the Nordøyane UHP domain; Fig. 1B; Vrijmoed et al. 2006,
2008; Scambelluri et al. 2008; Spengler et al. 2009; van
Roermund 2009a, b). The Nordøyane UHP domain extends
from the islands of Nordøyane to the nearby mainland, and
includes the nor thernmost UHP rocks exposed in the WGR
(Butler et al. 2013).
The sample discussed in this paper was obtained from the
Proterozoic Baltica basement exposed on Otrøy in the north-
western part of the WGR in the Nordøyane UHP domain
(Fig. 1B, C). A simplified geologic map of the island is shown
in Figure 1C. Otrøy is characterized by E–W to NNE–SSW
trending belts of basement rocks. These belts consist of inter-
layered migmatitic or augen orthogneisses and well layered
dioritic-gneisses (resembling the so-called Ulla Gneiss sensu
Terry & Robinson 2004) with abundant lenses of eclogites that
preserve eclogite facies mineral assemblages to various
extents (Carswell et al. 2006), garnet peridotites, and minor
eclogitized gabbros (van Roermund 2009b). The dominant
ENE–WSW striking amphibolite facies foliation is subver-
tical, commonly associated with a well-developed subhori-
zontal E–W amphibolite-facies lineation (Spengler 2006).
In the northwestern part of the island, three occurrences of
Caledonized UHP Mg–Cr garnet-peridotite bodies are incor-
porated within the basement gneisses (van Roermund & Drury
1998; Brueckner et al. 2002; Carswell et al. 2006; van
Roermund 2009b).
The southern part of the island is separated from the nor-
thern part by the Midsund–Åkra shear zone (Fig. 1C). This major
shear zone is a greenschist-facies ductile shear zone with
a dominant strike-slip sense of displacement associated with
a well-developed subhorizontal lineation (Terry & Robinson
2004). The rocks belonging to the southern part form an assem-
blage of metasediments (Blåhø Nappe mica schists), metaba-
sites and orthogneisses. An extensive part of the basement
along the southern shores consist of homoge neous amphibo-
lite boudins and finely laminated, pinkish feldspathic gneiss
with deformed diabase dykes (Hollocher et al. 2007).
Analytical procedures
The mineral chemistry data presented below was deter-
mined using a JXA8530F Jeol Hyperprobe Field Emission
Electron Probe Microanalyser (FE-EPMA) at the Department
of Earth Sciences, Uppsala University, Sweden. The measure-
ments were carried out using a 15kV accelerating voltage and
a 10nA beam current. The counting times were 10 s for the
peaks and 5 s for the background. Both mineral and synthetic
oxide standards were used to calibrate the Kα lines for all
measured elements. The raw data was corrected according to
the PAP routine.
Results
Field observations
The Proterozoic Baltica basement exposed in an abandoned
quarry located in Midsund is shown on Figs. 1C & 2A.
The rocks exposed in this quarry consist mainly of migmatitic
banded dioritic gneiss (Fig. 2B) that are interlayered with
granitoidic augen-orthogneiss (Fig. 2C). These gneisses are
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GEOLOGICA CARPATHICA
, 2019, 70, 6, 471–482
affected by a penetrative, steeply dipping amphibolite-facies
foliation that strikes ~ENE–WSW. A linear shape fabric is
well defined by elongate grain aggregates of either K-fedspar
or quartz (commonly ribbons) and has a subhorizontal plunge
and ENE–WSW azimuth (Fig. 2D). Eclogites, retro-eclogites
and granulites occur as isolated lenses and boudins within
Fig. 2. Outcrop photos from a former quarry located in the western part of Otrøy Island, where the sample discussed in this paper is located,
showing the lithological and structural features of Proterozoic basement rocks of Baltica. A — Panoramic view of the entire outcrop from
the SW (from Google maps). B, C — Proterozoic basement consisting of (B) migmatitic banded dioritic gneiss interlayered with (C) Kfs-
augen-orthogneiss. D — Penetrative steeply dipping foliation striking ~ENE–WSW within augen-orthogneiss, with penetrative mineral linea-
tion defined by elongated K-feldspar and quartz. Lineation has subhorizontal plunge and ENE–WSW azimuth. E — Lens of eclogite and
retro-eclogite within the strongly foliated augen-orthogneiss. F — HP granulite embedded within the migmatitic banded dioritic gneiss.
G — Zoom in on a part of (F): HP granulite with the layered garnet showing the sample discussed in this paper.
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MIDSUND GRANULITE FROM OTRØY, WESTERN GNEISS REGION, NORWAY
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both the foliated augen-orthogneiss (Fig. 2E) and the migma-
titic banded dioritic gneiss (Fig. 2F, G).
Petrography and mineral chemistry
The Midsund granulite exhibits a grano- to nematoblastic
texture and is dominated by garnet, clinopyroxene, plagioclase
and quartz (Fig. 3A, B). A weak foliation is marked by less
abundant amphibole and biotite, minor apatite, rutile, and
titanite that occur sporadically in the matrix (Fig. 3A, B). Even
less abundant are phengite, ilmenite, zircon and K-feldspar.
Garnet forms subhedral to anhedral porphyroblasts and is
generally homogeneous in its composition in the range of
Alm
47–49
Grs
31–35
Prp
17–18
Sps
0.8–1.5
(Table 1, Fig. 3C). The only
exception in this pattern is the thin outermost rim that shows
a sharp increase of X
Alm
(up to 56 mol. %) and X
Fe
(from 72 to
75 %) that is accompanied by a simultaneous decrease of X
Grs
(down to 23 mol. %), while X
Prp
and X
Sps
remain relatively
consistent across the whole profile (Fig. 3C, D). Garnet con-
tains scarce inclusions of sodic clinopyroxene, phengite,
quartz, apatite, rutile, ilmenite and zircon, which presumably
represents a mineral assemblage entrapped during the pro-
grade to peak metamorphism. Seldom composite inclusions of
phengite partly replaced by biotite, and inclusions of amphi-
bole and plagioclase were found in fissured garnet grains,
indicating their retrograde origin. Rarely, multi-phase inclu-
sions, somewhat resembling melts (see e.g., Ferrero et al.
2015), composed of K-feldspar, biotite, plagioclase and/or
pure albite are also found in the garnet (Fig. 3E).
Clinopyroxene of diopside composition rarely occurs as elon-
gated inclusions (not exceeding 200 µm) in garnet (Table 1,
Fig. 3D). Most commonly, clinopyroxene forms poikilitic inter-
growths with plagioclase, quartz and amphibole in the matrix
(Fig. 3B, F), and its composition shows a broad range, i.e.
X
Di
=79–93 mol. %, X
Jd
=6–18 mol. % (X
Na
=0.07–0.21) and
X
Aeg
=1–4 mol. % (Table 1). Matrix clinopyroxene is generally
well preserved and is only locally replaced by amphibole
(Fig. 3F).
Phengite has only been found as inclusions in garnet and
partially replaced by biotite (Fig. 3G). The Si content varies
between 3.17 and 3.20 a.p.f.u. (Table 2).
Plagioclase occurs in four textural positions. Most com-
monly, it forms subhedral grains (up to 600 µm) evenly
distributed in the matrix (Fig. 3H), hereinafter referred to
as matrix plagioclase. It is a Na-rich variety with X
Ab
=75–
78 mol. %, X
An
=17–22 mol. % and X
Or
=3–5 mol. % (Table 3).
Plagioclase is also a major constituent of poikilitic inter-
growths with clinopyroxene (Fig. 3B, F). The chemical com-
position of this plagioclase corresponds to X
Ab
=75–77 mol. %,
X
An
=19–21 mol. % and X
Or
=2–4 mol. % (Table 3). Sporadically,
plagioclase also forms intergrowths with biotite and mono-
mineral inclusions in garnet.
Amphibole predominantly forms euhedral to subhedral, uni-
formly oriented elongated grains in the matrix. They contain
abundant quartz and apatite inclusions, and is rarely observed
to have partly replaced poikiloblastic clinopyroxene (Fig. 3F),
but it also forms intergrowth with quartz. In both textural
positions, amphibole has a pargasitic composition (Table 2).
Biotite mainly forms subhedral flakes (with sizes varying
from 50 µm to 1.5 mm) located in the matrix. Less common
larger flakes (> 500 µm) are typically oriented (sub-)parallel
to amphibole (Fig. 3B). However, the orientation of some
grains is at a high-angle to the amphiboles. Biotite is also
found as inclusions partly replacing phengite in garnet
(Fig. 3G).
Quartz is an abundant mineral that is evenly distributed in
the matrix (Fig. 3A, B). Quartz grains often display polygonal
textures with straightened grain boundaries (e.g., Humphreys
& Hatherley 1995) and distinctive triple junctions at the grain
boundaries (e.g., Kruhl 2001). These preserved textures are
indi cative of the high-temperature GBAR (grain boundary
area reduction) process.
In summary, based on the above-mentioned petrographic
description, it is inferred that the studied rock underwent
HP metamorphism, which was followed by a lower pressure
granulite facies overprint. The latter resulted in the stabi-
lization of the peak temperature assemblage composed of
garnet + plagioclase + clinopyroxene + ilmenite ± amphibole
± melt.
Pressure–temperature estimates
Isochemical phase diagrams have been calculated using
the Perple_X 6.8.5 software package (Connolly 1990, 2005).
The internally consistent thermodynamic database by Holland
& Powell (2011) has been used for calculations in the Na
2
O–
CaO–K
2
O–FeO–MgO–MnO–Al
2
O
3
–SiO
2
–H
2
O–TiO
2
(NCKFMMnASHT) system. The granulite chemical composi-
tion was determined by areal-EDS analyses performed in
the same electron microprobe laboratory as the WDS mea-
surements. Results are presented in Figure 4. To estimate
the minimum fluid content required to produce melt within
the granulite-facies assemblage observed in the thin section,
the P–X
H2O
pseudosection was modelled. A pure H
2
O fluid
was assumed for the modelling. The pseudosection was calcu-
lated in a P–T space of 1–2 GPa and 650–1100 °C and
a constant H
2
O content of 0.40 wt. % (Fig. 4). Solution models
for garnet, biotite and ilmenite are from White et al. (2007),
white mica and melt from White et al. (2014), clinopyroxene
from Green et al. (2007), plagioclase from the ternary feldspar
model of Holland & Powell (2003), and amphibole from
Green et al. (2016) have been selected.
Compositional isopleths of X
Mg
(X
Mg
=Mg/Mg+Fe) in gar-
net, albite content in plagioclase and X
Na
(X
Na
=Na/Na+Ca) in
clinopyroxene have been combined to estimate P–T condi-
tions of equilibration. Isopleths intersect within the field con-
taining the phase assemblage of melt + plagioclase + garnet +
clino pyroxene + amphibole + ilmenite (Fig. 4). The P–T space
encompassed by the intersection of the isopleths shows that
the granulite assemblage observed in the studied sample has
formed at HP and HT conditions of 1.32–1.45 GPa and
875–970 °C.
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GEOLOGICA CARPATHICA
, 2019, 70, 6, 471–482
Fig. 3. A, B — Photomicrographs in a plane polarized light. (A) Typical microtexture and composition of granulite (sample IK14-11-A3) with
garnet (Grt), clinopyroxene (Cpx), quartz (Qz), plagioclase (Pl), amphibole (Am), biotite (Bt), minor titanite (Ttn), rutile (Rt) and apatite (Ap).
(B) Typical garnet and retrogressed poikiloblastic clinopyroxene with plagioclase and quartz intergrowths. C — Compositional profile across
the garnet presented in (D) shows variations in mole fractions of the X
Fe
and almandine (Alm), grossular (Grs), pyrope (Prp) and spessartine
(Sps) components. D — BSE image of a garnet with a trajectory line marked along which a step line profile was carried out. Garnet shows
an inclusion of clinopyroxene and it is surrounded by amphibole, biotite and clinopyroxene. E — BSE image of a multiphase inclusion of
biotite + plagioclase + K-feldspar (Kfs) + albite (Ab) in garnet. F — Photomicrograph in a plane polarized light showing amphibole replacing
poikiloblastic clinopyroxene. G — BSE image of a composite inclusion of phengite (Ph) and biotite in garnet. H — Photomicrograph in
a crossed polarized light showing plagioclase with polysynthetic twinning evenly distributed in the matrix together with biotite, quartz, clino-
pyroxene and garnet.
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MIDSUND GRANULITE FROM OTRØY, WESTERN GNEISS REGION, NORWAY
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Mineral
Grt
Grt
Grt
Grt
Grt
Grt
Grt
Grt
Grt
Grt
Cpx
Cpx
Cpx
Cpx
Cpx
Cpx
Cpx
Cpx
Cpx
Cpx
Position
Rim
Rim
Rim
Cor
e
Cor
e
Cor
e
Cor
e
Rim
Rim
Rim
Pbl
Pbl
Pbl
Pbl
Pbl
Pbl
Incl
Incl
Incl
Incl
SiO
2
37.72
38.10
38.30
38.13
38.34
37.86
37.76
37.61
37.46
37.77
51.39
51.32
51.13
50.63
50.96
50.69
50.02
49.1
1
51.13
51.63
Ti
O
2
0.06
0.02
0.08
0.12
0.02
0.09
0.1
1
0.06
0.09
0.01
0.22
0.34
0.28
0.33
0.32
0.36
0.35
0.33
0.31
0.31
Al
2
O
3
21.61
21.79
21.82
21.85
21.84
22.20
21.76
21.40
21.56
21.50
7.17
3.88
7.60
5.20
7.84
6.63
6.95
6.22
6.10
5.65
CaO
8.55
10.38
11.37
12.14
12.20
12.55
13.01
11.30
10.64
9.99
18.88
21.83
18.71
21.1
1
19.16
19.74
21.83
22.09
21.95
22.32
MgO
4.82
4.62
4.69
4.85
4.75
4.51
4.58
4.84
4.92
4.94
9.92
11.56
9.71
10.89
10.02
9.63
10.94
10.76
11.19
12.02
MnO
0.93
0.86
0.68
0.48
0.53
0.40
0.39
0.72
0.70
0.73
0.09
0.1
1
0.12
0.06
0.09
0.14
0.08
0.08
0.00
0.04
FeO
26.21
23.81
22.89
22.41
22.38
22.47
22.10
23.22
22.88
23.87
8.77
9.89
9.23
9.43
9.19
9.99
9.63
9.35
8.15
7.43
Na
2
O
0.00
0.06
0.01
0.05
0.05
0.07
0.09
0.04
0.02
0.04
2.84
0.96
2.58
1.37
2.36
1.89
1.01
0.95
1.29
1.26
K
2
O
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.01
0.03
0.00
0.02
Total
99.99
99.81
99.87
100.09
100.16
100.20
99.79
99.22
98.38
98.98
99.37
100.05
99.54
99.1
1
100.15
99.18
100.96
99.02
100.21
100.89
O
12.00
12.00
12.00
12.00
12.00
12.00
12.00
12.00
12.00
12.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00
Si
2.95
2.97
2.97
2.95
2.96
2.92
2.93
2.94
2.95
2.97
1.90
1.92
1.90
1.90
1.88
1.91
1.85
1.85
1.89
1.89
Ti
0.00
0.00
0.00
0.01
0.00
0.01
0.01
0.00
0.01
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
Al
1.99
2.00
2.00
1.99
1.99
2.02
1.99
1.97
2.00
1.99
0.31
0.17
0.33
0.23
0.34
0.29
0.30
0.28
0.27
0.24
Ca
0.72
0.87
0.95
1.01
1.01
1.04
1.08
0.95
0.90
0.84
0.75
0.87
0.74
0.85
0.76
0.79
0.86
0.89
0.87
0.88
Mg
0.56
0.54
0.54
0.56
0.55
0.52
0.53
0.56
0.58
0.58
0.55
0.64
0.54
0.61
0.55
0.54
0.60
0.60
0.62
0.66
Mn
0.06
0.06
0.04
0.03
0.03
0.03
0.03
0.05
0.05
0.05
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe
2+
1.71
1.55
1.49
1.45
1.45
1.45
1.43
1.52
1.51
1.57
0.20
0.27
0.25
0.25
0.24
0.30
0.24
0.22
0.23
0.19
Fe
3+*
0.07
0.04
0.04
0.05
0.04
0.01
0.05
0.07
0.02
0.04
Na
0.00
0.01
0.00
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.20
0.07
0.19
0.10
0.17
0.14
0.07
0.07
0.09
0.09
K
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Total
8.00
8.00
8.00
8.00
8.00
8.00
8.00
8.00
8.00
8.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
Jad
17.48
5.78
17.55
8.68
15.87
13.79
6.63
5.89
8.91
8.03
Di
78.61
92.79
80.47
89.54
82.10
85.58
92.17
92.51
90.28
90.58
Aeg
3.91
1.43
1.97
1.77
2.04
0.63
1.20
1.60
0.81
1.39
X
Na
0.21
0.07
0.20
0.1
1
0.18
0.15
0.07
0.07
0.09
0.09
X
Mg
24.69
25.70
26.75
27.84
27.45
26.35
26.98
27.81
27.71
26.95
73.09
70.69
68.32
71.01
69.68
64.23
71.28
73.30
73.02
77.94
Alm
56.13
51.52
49.22
47.58
47.60
47.82
46.69
49.35
49.75
51.66
Grs
23.46
28.78
31.33
33.02
33.25
34.22
35.22
30.77
29.64
27.70
Prp
18.40
17.82
17.98
18.36
18.01
17.1
1
17.25
18.34
19.07
19.06
Sps
2.02
1.88
1.47
1.04
1.14
0.86
0.84
1.55
1.55
1.59
Jad = Al/(Al+Fe
3+
)×(100
−
Di), Di = (Ca+Fe
2+
+Mg)/(Ca+Fe
2+
+Mg)+(2×Na)×100,
Aeg = Al/(Al+Fe
2+
)×(100
−
Di), XNa = Na/(Na+Ca), XMg = Mg/(Fe
2+
+Mg)×100,
Alm = Fe
2+
/(Fe
2+
+Mg+Ca+Mn)×100,
Grs = Ca/(Ca+Fe
2+
+Mg+Mn)×100, Prp = Mg/(Mg+Fe
2+
+Ca+Mn)×100, Sps = Mn/(Mn+Fe
2+
+Mg+Ca)×100, *Fe
3+
has been estimated based on char
ge balance; Pbl — poikiloblast; Inlc — inclusion in garnet
Table 1:
Representative microprobe analyses of garnet and clinopyroxene.
478
HOLMBERG, BUKAŁA, JEANNERET, KLONOWSKA and MAJKA
GEOLOGICA CARPATHICA
, 2019, 70, 6, 471–482
Discussion and final remarks
Garnet grains commonly record valuable information
regarding the evolution of a rock. Even though the garnet in
the Midsund granulite is nearly completely homogenized and
is inclusion-poor, it still provides insight into the prograde to
peak-pressure metamorphic evolution of the rock. Rare inclu-
sions of sodic clinopyroxene and phengitic mica are inter-
preted to have formed during the prograde to near peak-pressure
stages of the P–T path. The peak-pressure conditions were
impossible to estimate for the studied rock due to severe post-
peak pressure processes that lead to the obliteration of
the peak assemblage. However, it can be speculated that they
were not significantly different from the P–T conditions for
Scandian re-equilibration that was calculated for the nearby
Ugelvik garnet websterite (c. 3–4 GPa at 800–900 °C, their
M3 assemblage, Spengler et al. 2009) or the peak P–T condi-
tions estimated for an UHP eclogite (c. 3–4 GPa at 750–850 °C,
Kylander-Clark et al. 2007) located in close proximity to
the Midsund granulite.
Mineral
Ph
Ph
Ph
Ph
Am
Am
Am
Am
Position
Incl
Incl
Incl
Incl
Mtx
Mtx
Mtx
Mtx
SiO
2
48.13
47.63
48.72
49.07
41.01
42.25
40.79
41.56
TiO
2
1.21
1.23
1.00
1.06
1.42
1.78
2.09
1.85
Al
2
O
3
30.76
31.18
31.94
31.81
13.82
12.91
13.34
13.37
CaO
0.16
0.14
0.12
0.13
11.47
11.38
11.56
11.44
MgO
3.00
2.54
2.21
2.45
9.81
10.66
10.18
10.25
MnO
0.01
0.00
0.10
0.03
0.03
0.08
0.06
0.03
FeO
2.95
2.43
1.90
2.16
16.10
15.79
15.61
15.59
Na
2
O
0.10
0.14
0.14
0.14
1.87
1.93
1.91
1.85
K
2
O
10.38
10.74
10.66
10.66
1.59
1.56
1.63
1.50
Total
97.28
96.58
97.19
98.03
97.12
98.34
97.17
97.44
O
11.00
11.00
11.00
11.00
23.00
23.00
23.00
23.00
Si
3.18
3.17
3.20
3.20
6.21
6.28
6.16
6.23
Ti
0.06
0.06
0.05
0.05
0.16
0.20
0.24
0.21
Al
2.40
2.45
2.47
2.45
2.47
2.26
2.38
2.36
Ca
0.01
0.01
0.01
0.01
1.86
1.81
1.87
1.84
Mg
0.30
0.25
0.22
0.24
2.22
2.36
2.29
2.29
Mn
0.00
0.00
0.01
0.00
0.00
0.01
0.01
0.00
Fe
2+
0.16
0.14
0.10
0.12
2.04
1.82
1.88
1.84
Fe
3+*
0.00
0.14
0.10
0.11
Na
0.01
0.02
0.02
0.02
0.55
0.56
0.56
0.54
K
0.88
0.91
0.89
0.89
0.31
0.30
0.31
0.29
Total
7.00
7.01
6.97
6.98
15.82
15.74
15.80
15.72
*Fe
3+
has been estimated based on charge balance; Mtx — matrix; Inlc — inclusion in garnet
Mineral
Pl
Pl
Pl
Pl
Pl
Pl
Pl
Pl
Pl
Pl
Position
Mtx
Mtx
Mtx
Mtx
Mtx
Mtx
Pbl
Pbl
Pbl
Pbl
SiO
2
63.94
63.65
62.95
62.64
62.20
62.99
62.83
62.36
63.16
62.51
Al
2
O
3
21.67
21.91
22.03
22.04
22.56
21.94
22.60
23.01
22.08
22.59
CaO
3.42
3.70
3.89
3.86
4.49
3.97
4.42
4.68
3.90
4.46
Na
2
O
8.66
9.01
9.08
8.90
8.57
9.15
8.56
8.73
8.77
8.69
K
2
O
0.87
0.72
0.69
0.64
0.56
0.58
0.59
0.40
0.64
0.54
Total
98.56
98.99
98.64
98.08
98.38
98.63
99.00
99.18
98.55
98.79
O
8.00
8.00
8.00
8.00
8.00
8.00
8.00
8.00
8.00
8.00
Si
2.86
2.84
2.83
2.82
2.80
2.83
2.81
2.78
2.83
2.80
Al
1.14
1.15
1.17
1.17
1.20
1.16
1.19
1.21
1.17
1.19
Ca
0.16
0.18
0.19
0.19
0.22
0.19
0.21
0.22
0.19
0.21
Na
0.75
0.78
0.79
0.78
0.75
0.80
0.74
0.76
0.76
0.76
K
0.05
0.04
0.04
0.04
0.03
0.03
0.03
0.02
0.04
0.03
Total
4.97
4.99
5.01
5.00
4.99
5.01
4.98
5.00
4.98
4.99
XAn (Ca)
16.99
17.73
18.40
18.63
21.73
18.71
21.44
22.33
19.00
21.41
XAb (Na)
77.86
78.14
77.72
77.72
75.04
78.02
75.14
75.38
77.30
75.50
XOr (K)
5.15
4.13
3.89
3.66
3.23
3.27
3.42
2.29
3.71
3.09
Mtx — matrix; Pbl — forming poikilitic intergrowths with clinopyroxene
Table 2: Representative microprobe analyses of phengite and amphibole.
Table 3: Representative microprobe analyses of plagioclase.
479
MIDSUND GRANULITE FROM OTRØY, WESTERN GNEISS REGION, NORWAY
GEOLOGICA CARPATHICA
, 2019, 70, 6, 471–482
The thermodynamic phase equilibrium modelling suggests
the HT equilibration conditions in the stability field of
melt + plagioclase + garnet + clinopyroxene + amphibole + ilme-
nite (Fig. 4), thus indicating a favorable scenario for the stabi-
lization of retrograde plagioclase in the observed assemblage.
It is envisioned that the plagioclase intergrown with clinopy-
roxene should have formed earlier during decompression due
to the breakdown of omphacite. Hence, the large plagioclase
grains in the matrix that show textural equilibrium with the
surrounding phases are considered to represent the part of
the equilibrium assemblage. It is inferred here that it could
have formed as a result of partial melt crystallization upon
cooling. However, not much partial melt has been observed in
the outcrop, hand specimens and even thin sections. Only rare
multi-phase inclusions in garnet containing K-feldspar, pla-
gioclase, pure albite and biotite may be indicative for partial
melting and thus could confirm melt presence during the rock
evolution (e.g., Ferrero et al. 2015). Alternatively, they might
have resulted from a breakdown of an unidentified prograde
Na-, Ca- and K-bearing hydrous mineral (white mica plus
zoisite?), but the preserved remnants of white mica do not
contain increased amount of Na nor Ca. However, the model-
led pseudosection does predict partial melting. Hence, it
is considered that the partial melting must have affected
the studied rock to some degree, likely during the earliest
stages of decompression from peak pressure conditions.
The other metamorphic changes that occurred during decom-
pression are expressed by the formation of diopside–pla-
gioclase poikiloblasts at the expense of clinopyroxene with
a more omphacitic compositions, by the replacement of
phengite by biotite, and by growth of the matrix plagioclase,
amphibole and biotite, as well as replacement of relict rutile
by titanite. Especially the latter phenomenon is interpreted to
have occurred at final stages of the metamorphic cycle under
amphibolite facies conditions. Also, the sharp change of the
composition of garnet in the outermost rim can be explained
by retrogressive diffusion and exchange between garnet in
mutual contact with clinopyrexene, amphibole and biotite
(Fig. 3D) during decompression to granulite and farther
decom pression and cooling to amphibolite facies conditions.
The obtained P–T conditions for decompressional HT equi-
libration of the Midsund granulite are in line with those
recently calculated for comparable HP granulites occurring
just north-east of the study area, as presented by Engvik et al.
(2018). These authors estimated minimum P–T conditions for
HP granulites at 1.4–1.8 GPa and 900–1100 °C. It also sup-
ports the observations made by Ganzhorn et al. (2014), who
reported pervasive partial melting and HT equilibration of
Fig. 4. P–T pseudosection of the granulite calculated in the NCKFMMnASHT system at conditions of T = 650–1100 °C and P = 1–2 GPa. Green
field outlines the inetersection of compositional isopleths of X
Ab
, X
Na
in clinopyroxene and X
Mg
in garnet. Mineral abbreviations: Am — amphi-
bole, Bt — biotite, Cpx — clinopyroxene, Grt — garnet, Ilm — ilmenite, Mu — muscovite, Pl — plagioclase, Qz — quartz, Rt — rutile,
Sph — sphene.
480
HOLMBERG, BUKAŁA, JEANNERET, KLONOWSKA and MAJKA
GEOLOGICA CARPATHICA
, 2019, 70, 6, 471–482
felsic gneisses in the study region. Hence, the results obtained
in this study are in agreement with the general, regional trend
of a temperature gradient increase towards this part of the
WGR as suggested e.g. by Cuthbert et al. (2000). As noted by
Engvik et al. (2018), the WGR was traditionally thought to be
a relatively cold UHP terrane. Their results, coupled with
these presented herein and other observations of granulitized
eclogites from Nordøyane (e.g., Larsen et al. 1998; Butler et
al. 2013) and farther northeast from northernmost Vestranden
in the Roan area (Möller 1988), show that this part of the
WGR must have undergone regional scale HT re-equilibration
of the eclogitized orogenic root during the terminal stages of
the Scandian collision. This, in turn, broadens our understan-
ding of the Caledonian orogenic cycle and shows that the
Scandinavian Caledonides may share more similarities with
other hot orogens, such as the Bohemian Massif (but see also
e.g., O’Brien & Rötzler 2003; Medaris et al. 2018), than pre-
viously envisioned. It also shows a clear need for further
petrological exploration of the garnet–clinopyroxene–plagio-
clase rocks that are within both the Parautochthon and alloch-
thons of the Scandinavian Caledonides in order to deliver
comprehensive data on the evolution of this mountain belt.
Acknowledgements: Simon Cuthbert and Dirk Spengler
are thanked for their constructive reviews. Chris Barnes is
acknowledged for help with linguistic correction, and Marian
Janák as well as Milan Kohút for editorial works. This research
was supported by the National Science Centre (Poland)
funded research project CALSUB no. 2014/14/ST10/00321.
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