GEOLOGICA CARPATHICA
, APRIL 2018, 69, 2, 117–127
doi: 10.1515/geoca-2018-0007
www.geologicacarpathica.com
Carbon cycle history through the Middle Jurassic
(Aalenian – Bathonian) of the Mecsek Mountains,
Southern Hungary
GREGORY D. PRICE
1,
, ISTVÁN FŐZY
2
and ANDRÁS GALÁCZ
3
1
School of Geography, Earth & Environmental Sciences, University of Plymouth, Drake Circus, Plymouth, PL4 8AA, United Kingdom;
g.price@plymouth.ac.uk
2
Department of Palaeontology and Geology, Hungarian Natural History Museum, POB 137, Budapest, H-1431 Hungary; fozy.istvan@nhmus.hu
3
Department of Palaeontology,
Eötvös Loránd University, Pázmány P. sétány 1/C, Budapest, H-1117 Hungary; galacz@ludens.elte.hu
(Manuscript received June 9, 2017; accepted in revised form January 16, 2018)
Abstract: A carbonate carbon isotope curve from the Aalenian–Bathonian interval is presented from the Óbánya valley,
of the Mecsek Mountains, Hungary. This interval is certainly less well constrained and studied than other Jurassic time
slices. The Óbánya valley lies in the eastern part of the Mecsek Mountains, between Óbánya and Kisújbánya and provides
exposures of an Aalenian to Lower Cretaceous sequence. It is not strongly affected by tectonics, as compared to other
sections of eastern Mecsek of the same age. In parts, a rich fossil assemblage has been collected, with Bathonian
ammonites being especially valuable at this locality. The pelagic Middle Jurassic is represented by the Komló Calcareous
Marl Formation and thin-bedded limestones of the Óbánya Limestone Formation. These are overlain by Upper Jurassic
siliceous limestones and radiolarites of the Fonyászó Limestone Formation. Our new data indicate a series of carbon
isotope anomalies within the late Aalenian and early-middle Bajocian. In particular, analysis of the Komló Calcareous
Marl Formation reveals a negative carbon isotope excursion followed by positive values that occurs near the base of the
section (across the Aalenian–Bajocian boundary). The origin of this carbon-isotope anomaly is interpreted to lie in
significant changes to carbon fluxes potentially stemming from reduced run off, lowering the fertility of surface waters
which in turn leads to lessened primary production and a negative δ
13
C shift. These data are comparable with carbonate
carbon isotope records from other Tethyan margin sediments. Our integrated biostratigraphy and carbon isotope
stratigraphy enable us to improve stratigraphic correlation and age determination of the examined strata. Therefore, this
study of the Komló Calcareous Marl Formation confirms that the existing carbon isotope curves serve as a global standard
for Aalenian–Bathonian δ
13
C variation.
Keywords: Carbon, isotope stratigraphy, Aalenian, Bajocian, Óbánya, Mecsek, Hungary.
Introduction
The δ
13
C curve of the Aalenian–Kimmeridgian interval shows
a series of major Jurassic isotope events within the Aalenian,
early-middle Bajocian, Callovian and middle Oxfordian
(Hoffman et al. 1991; Bill et al. 1995; Jenkyns 1996; Weissert
& Mohr 1996; Bartolini et al. 1999; Rey & Delgado 2002;
O’Dogherty et al. 2006; Sandoval et al. 2008; Nunn et al.
2009; Price et al. 2016) recorded in both southern and northern
Tethyan margin sediments. The potential of these δ
13
C records
for regional and global correlation of ancient marine sedi-
ments is evident. Some of these excursions (e.g., during the
Oxfordian) are intrinsically coupled with climatic changes and
have been extensively studied in many parts of the world (e.g.,
Bill et al. 1995; Jenkyns 1996). With respect to the Middle
Jurassic interval (e.g., the Aalenian–Bathonian) it is the carbon
isotope curves of Bartolini et al. (1999) and Sandoval et al.
(2008) that often serve as a global standard (e.g., Ogg &
Hinnov 2012). Major carbon-cycle perturbations in the Middle
Jurassic are also recognised in terrestrial organic matter (fossil
wood) (Hesselbo et al. 2003). Although the excursions of
the Middle Jurassic have received only modest attention, they
occur on more than one continent and may thus serve for
global correlation of strata (e.g., Wetzel et al. 2013; Hönig &
John 2015; Dzyuba et al. 2017). The goal of this study is to
examine Aalenian–Bathonian carbon isotope stratigraphy from
Hungary for comparison. A further aim of this study is to
examine linkages between the δ
13
C record of past global biotic
and climatic change.
Geological setting
The Lower Jurassic of the Mecsek Mountains of Hungary
(Fig. 1) is characterized by coal bearing continental and
shallow marine siliciclastic sediments (Haas et al. 1999).
From Late Sinemurian times onwards, deposition consisted of
deeper marine hemipelagic facies with mixed siliciclastic–
carbonate lithologies (the Hosszúhetény and Komló Calca-
reous Marl formations, Raucsik & Merényi 2000). The site of
this hemipelagic marly and calcareous marly sedimentation
was most probably on or distally beyond the northern outer
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shelf of the Tethys Ocean (Fig. 2), whilst shallower conditions
occurred towards the western margins (Enay et al. 1993).
Although the precise age of the Komló Calcareous Marl
Formation is uncertain, an Aalenian to Bajocian age is indi-
cated (Forgó et al. 1966, Fig. 3). Overlying the Komló
Calcareous Marl Formation, in the Mecsek, is the pelagic
Bathonian–Callovian Óbánya Limestone Formation consisting
of thin-bedded limestones and marls (Galácz 1994). The Upper
Jurassic is represented by a siliceous limestone and radiolarite
(the Fonyászó Limestone) as well as thin-bedded limestone
(the Kisújbánya and Márévár limestones).
The Óbánya valley (Fig. 1) lies in the eastern part of the
Mecsek Mountains, between Óbánya and Kisújbánya and
provides exposures of the Komló Calcareous Marl Formation.
The succession is not strongly affected by tectonics, as com-
pared to other sections of eastern Mecsek of the same age
(Velledits et al. 1986). The exposed Aalenian and Bajocian
sediments (the Komló Calcareous Marl Formation) can be
seen as alternating limestone beds (0.2–0.5 m) and laminated
beds consisting of dark grey, spotted, bituminous, micaceous
marls (Fig. 4). The laminated beds become harder upwards
with increasing carbonate content (from 36 to 55 %; Velledits
et al. 1986). Aside from some bivalve and plant imprints
within the lower part of the succession, an ammonite (Ludwigia
sp.) has been found indicating an Aalenian age (Velledits et al.
1986). The total thickness of the Aalenian has been estimated
by Velledits et al. (1986) to be ~75 m although only the top
~25 m was exposed. Fossils from the middle part of the
succession include the ammonites Dorsetensia (at ~105 m)
and Stephanoceras (indicative of the Humphriesianum Zone),
bivalve moulds together with carbonized plant fragments
(Velledits et al. 1986). Age diagnostic ammonites (e.g., Lepto
sphinctes, Adabofoloceras of the Niortense Zone) are recorded
within the upper part of the Komló Calcareous Marl (Velledits
et al. 1986). The total thickness of sediments of Bajocian
age is ~170 m. The Komló Calcareous Marl is overlain by
a red calcareous marl and nodular limestone (Fig. 4) rich
in age diagnostic ammonites (e.g., Parkinsonia, Morphoceras
and Procerites) and pelagic microfossils (Galácz 1994).
This 20 m thick formation (the Óbánya Limestone For mation)
is of Bathonian age (Galácz 1994) and was
deposited in a pelagic environment. During this
time major flooding events also occur elsewhere
in northern Europe, with a peak trans gression
at the Bajocian–Bathonian boundary (Hallam
2001).
Materials and methods
For this study, 273 bulk carbonate samples were
derived from the outcrop of the Óbánya valley
(from 46°13’17” N, 18°24’15” E to 46°12’47” N,
18°23’20” E). Samples were taken from both
marl and limestone lithologies (Fig. 5). The ave-
rage spacing of samples was ~0.3 m. Subsamples
(250 to 400 micrograms) avoiding macrofossils
and sparry calcite veins, were then analysed for
stable isotopes using a GV Instruments Isoprime
Mass Spectrometer with a Gilson Multiflow
carbonate auto-sampler at Plymouth University.
Isotopic results were calibrated against the
NBS-19 international standard. Reproducibility
for both δ
18
O and δ
13
C was better than ± 0.1 ‰,
based upon duplicate sample analyses.
Results
The isotope results are presented in Figures 6
and 7. As isotopic analyses were undertaken from
both marl and limestone lithologies a comparison
of the isotopic composition of the two lithologies
can be made. For the limestone (n = 181) the
mean δ
13
C value is 1.0 ‰ and −3.5 ‰ for δ
18
O.
For the marl (n = 92) the mean δ
13
C value is less
Fig. 1. A — Map showing the location of the Óbánya valley within Hungary.
Grey inset box shows location of the Mecsek Mountains. B — Distribution
of Mesozoic volcanic and sedimentary units within the Mecsek Mountains from
Galácz (1994).
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Fig. 2. Middle Jurassic palaeogeographic map of the Western Tethyan realm (modified from Enay et al. 1993). Localities: 1 — Óbánya;
2 — Wadi Naqab, United Arab Emirates; 3 — Southern Iberia; 4 — Umbria-Marche Basin (Central Italy); 5 — Cabo Mondego, Portugal;
6 — Chaudon Norante, SE France.
Fig. 3. Lithostratigraphical scheme for the Jurassic deposits of the Mecsek Zone (Hungary) modified from Némedi Varga (1998) and
Főzy (2012).
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positive, 0.4 ‰ and −4.3 ‰ for δ
18
O. The greater number of
limestone vs. marl samples analysed reflects the generally
better exposure of the limestones and poorer quality of the
marl outcrops. It is for this reason that the carbon isotope
curve (Fig. 7) is plotted though the limestone data only. Using
Student’s T-Test the isotopic difference between limestones
and marls is also significant (at p < 0.05). These data are also
consistent with stable isotope data from Raucsik (1997)
who also isotopically analysed both limestone and marlstone
carbonate samples from the Komló Calcareous Marl Formation
(Fig. 6).
With respect to the carbon isotope stratigraphy (derived
from the limestone data) a number of features of the curve
are of particular note. Firstly, there is a negative excursion
followed by positive values occurring near the base of the
section (across the Aalenian–Bajocian boundary). The carbon-
isotope values then become more positive, reaching the most
positive values seen (at about 100 m height in Fig. 7). Although
showing a good deal of scatter, values remain fairly positive,
until towards the top of the Komló Calcareous Marl Formation
where there is a drop in
13
C values (at 166 m). Carbon isotope
values then increase again, where they reach a maximum
(of 2.4 ‰), within the Bathonian. The carbon isotope data
derived from the marls also follow this trend.
The wide range of oxygen isotopes and the low values,
possibly points to a diagenetic overprint. Although a tempera-
ture control on oxygen isotopes cannot be excluded (see below),
deep burial diagenesis and precipitation of calcite cement,
commonly results in depleted in δ
18
O values (Hudson 1977;
Weissert 1989: Hönig & John 2015). The preservation of δ
13
C
values or trends during carbonate diagenesis is, however, quite
typical, and is likely due to the buffering effect of carbonate
carbon on the diagenetic system, as this is the largest carbon
reservoir (e.g., Scholle & Arthur 1980; Weissert 1989). Hence,
with respect to the oxygen isotope data, a diagenetic overprint
affecting the samples analysed and results is likely. Although
showing some scatter, oxygen isotope values remain fairly
negative at the base of the section (the Aalenian) and become
increasingly more positive upsection. The most positive
oxygen isotope values are identified in the Bathonian (the Óbánya
Limestone Formation).
Discussion
Limestone–marl alternations
The conspicuous limestone–marl alternations of the Komló
Calcareous Marl Formation are likely to be caused by temporal
variations in environmental parameters. It is generally
accepted that the cause of the cyclical alternation of limestone
beds and marls represents a direct response to changes in envi-
ronmental conditions, such as productivity cycles (e.g.,
Wendler et al. 2002); dilution, i.e. changes in the influx of
terrigenous non-carbonate material (e.g., Raucsik 1997;
Weedon & Jenkyns 1999) or changes in input of carbonate
mud from adjacent shallow-water carbonate factories (e.g.,
Pittet & Strasser 1998). Based on stable isotope data, Raucsik
(1997) suggested that the higher δ
13
C of the limestones was
associated with higher productivity, whilst terrigenous dilution
may have formed the limestone-marlstone alternation. Given
that the data presented here are consistent with the data of
Raucsik (1997), in that the limestones typically record more
positive δ
13
C values (Fig. 6), the same conclusion could be
reached. A similar pattern could also be related to relatively
short term changes in the export of neritic carbonate mud,
as the δ
13
C of neritic muds, derived from relatively shallow
waters, tend to show more positive values than carbonate ooze
produced by planktonic organisms (e.g., Swart & Eberli 2005).
Indeed, Bajocian shallow-water carbonate factories on the
southern Tethyan shelf (Leinfelder et al. 2002) are likely to
show relatively positive carbon isotope values, although are
somewhat distal to the study site of hemipelagic sedimen-
tation on northern outer shelf of the Tethys Ocean (Fig. 2).
The Bajocian was a time of widespread oolite formation along
the Northern (and southern) Tethys margin (Wetzel et al. 2013).
Isotope values from these Northern Tethyan oolites (Wetzel et
al. 2013) do not show particularly positive values expected
for aragonite oolites. Indeed textures indicate that these oolites
were calcitic (Wetzel et al. 2013) (i.e. a calcite sea sensu
Sandberg 1983) and therefore this region exporting aragonite
during this time appears unlikely. Of note is that the oxygen
isotope data for the marls are more negative than the data
derived from the limestones (Fig. 6), a pattern consistent with
carbonate ooze produced in relatively warm surface waters.
Bodin et al. (2016), have also suggested lithological, rather
than oceanographic controls on δ
13
C trends (e.g., during
the earliest Toarcian of Morocco), whereby neritic δ
13
C
micrite
signatures show more positive values than carbonate ooze
produced by planktonic organisms. Changes in carbon isotope
values in marine carbonate successions have also been
attributed to changes in organic matter remineralization and
subaerial exposure around hardgrounds and subsequent carbo-
nate precipitation from meteorically influenced fluids (e.g.,
Immenhauser et al. 2002; Hönig & John 2015). Evidence for
subaerial exposure (e.g., signs of palaeokarst) was not observed
in the Óbánya valley.
Climatic and eustatic influences on carbon cycle changes
The negative excursion followed by positive values that
occurs near the base of the section (across the Aalenian–
Bajocian boundary), observed in this study, appears to cor-
relate with a major carbon cycle perturbation recognized
elsewhere (Fig. 8) as a widespread phenomenon on the basis
of its carbon–isotope expression in both oceanic (Bartolini et
al. 1996; O’Dogherty et al. 2006; Suchéras-Marx et al. 2012;
Hönig & John 2015) and terrestrial reservoirs (Hesselbo et al.
2003). It cannot be excluded that an earlier negative excursion
followed by positive values occurring in the Aalenian
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Fig. 4. A, B — Sections of the Komló Calcareous Marl Formation in the Óbánya valley, (notebook for scale). C — The Óbánya Limestone
Formation. D — Upper Jurassic siliceous limestones and radiolarites of the Fonyászó Limestone Formation.
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Concavum Zone at Agua Larga (O’Dogherty et al. 2006;
Sandoval et al. 2008), is correlatable with the lowermost
negative excursion. However, this possibility is not favoured
as no sizable negative shift is located above, in the Bajocian
part of the sucession. Carbon isotopes reach their most posi-
tive values, within the Óbánya succession, during the Early to
mid-Bajocian, before declining across the Bajocian–Bathonian
boundary. This same trend, is seen, for example in the
Terminilletto section, Apennines, Italy (Bartolini et al. 1999)
and the Betic Cordillera of southern Spain (O’Dogherty et al.
2006). Although there are evident differences in facies between
these sections, due to deposition under differing conditions
across the Tethys Ocean, the δ
13
C signatures are similar.
The carbon-isotope trends are therefore likely to represent at
least supraregional perturbations in the carbon cycle. Hence,
wide scale mechanisms need to be considered to account for
the observed trends.
Gradual negative carbon isotope excursions in the geolo-
gical record have, for example, been explained by reduced
primary production (e.g., Weissert & Channell 1989) whereby,
increasingly oligotrophic conditions, caused by reduced run
off and nutrient fluxes to the oceans, lower the fertility of
surface waters which in turn leads to lessened primary produc-
tion and a negative δ
13
C shift. Such a mechanism for δ
13
C
decreases has been associated with regressive conditions in
the latest Jurassic Tethyan seaway (e.g., Weissert & Channell
1989; Tremolada et al. 2006). During the Aalenian–Bajocian
boundary interval δ
13
C decreases have also been correlated
with regressive intervals (Sandoval et al. 2008). O’Dogherty
et al. (2006) also point out the coincidence between carbon
cycle perturbations and major changes in marine biota. For
example the latest Toarcian–Early Aalenian is marked by the
coexistence of very low radiolarian content, high proportions
of the nannofossil Schizosphaerella spp., and moderate pro-
portions of C. crassus, indicative of oligotrophic to meso-
trophic palaeoceanographic conditions (Aguado et al. 2008).
Although, there is no evidence of a regressive Aalenian–
Bajocian boundary interval at Óbánya, a significant regressive
event in Europe took place in Late Aalenian times (e.g.,
Hardenbol et al. 1998; Haq & Al-Qahtani 2005) followed by
Early Bajocian transgression and deepening (Hallam 2001).
As noted by Hallam (2001), Underhill & Partington (1993)
demonstrated that the Aalenian eustatic sea-level fall in the
Jurassic was in fact a phenomenon of regional tectonics.
Within Europe the effects of an Early Bajocian transgression
can be recognised widely, for example, in Morocco (Bodin et
al. 2017), north eastern Spain (e.g., Aurell et al. 2003) and in
the Jura Mountains of southern France (e.g., Razin et al. 1996).
Major perturbations in the carbon cycle have also been asso-
ciated with pulses of magmatism (e.g., Pálfy et al. 2001;
Wignall 2001; Hesselbo et al. 2003). However, the carbon
isotope excursion reported here and any association with
a large pulse of magmatism is not clearly demonstrated. For
example, radiometric data from the Karoo basalts indicates
that the main volume of the Karoo Large Igneous Province
(LIP) was emplaced between 181 and 184 Ma (i.e. during the
Fig. 5. A — Photomicrograph of the limestone lithology (from the
Komló Calcareous Marl Formation) dominated by calcite micro-
spar (sample OB115, scale bar 1 mm). Small patches of coarser
sparry calcite may have formed as a cement during diagenesis
within primary porosity or by neomorphism of aragonite.
B — Photomicrograph of marl lithology (from the Komló
Calcareous Marl Formation) showing abundant small sparry
bioclasts, including crinoids within a micritic and organic rich
matrix (sample OB546, scale bar 0.2 mm). C — Photomicrograph
of the Óbánya Limestone Formation showing abundant sparry
small bioclast fragments within a muddy matrix (sample OB125,
scale bar 0.2 mm).
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Late Pliensbachian to Early Toarcian) with limited late
stage basaltic activity at 176 Ma (e.g., Jourdan et al. 2008).
Younger episodic magmatic activity, associated with the
break- up of Gondwana following the formation of the Karoo
LIP, is reported from Patagonia and the Antarctic Peninsula
(Pankhurst et al. 2000). Aalenian–Bathonian volcanism is also
reported from the Crimea (Meijers et al. 2010), the Caucasus
region (Odin et al. 1993) and Mexico (Rubio-Cisneros &
Lawton 2011). Interestingly, the Aalenian–Early Bajocian
interval also overlaps with the birth of the Pacific Plate and
a major pulse of subduction related magmatism (Bartolini &
Larson 2001; Koppers et al. 2003). Evidence for the impact of
this magmatic activity can be assessed through
87
Sr /
86
Sr data.
The Aalenian–Early Bajocian seawater
87
Sr /
86
Sr curve shows,
however, a flat segment alluding to the limited impact of
this magmatic activity. This contrasts with the relatively rapid
fall in the seawater
87
Sr /
86
Sr ratio seen through the Late
Bathonian and Early Callovian (Wierzbowski et al. 2012).
Hence it appears likely that the volcanogenic CO
2
associated
with these events certainly represents a potential source for
light carbon, although possibly not of sufficient magnitude
and sufficiently light to achieve the observed isotopic change.
Alternatively, an injection of isotopically light carbon into
the ocean and atmosphere from a remote source, such as
methane from clathrates, wetlands, or thermal metamorphism
organic rich sediments (e.g., McElwain et al. 2005; Bachan et
al. 2012) has been considered as means to explain negative
carbon isotope excursions. Similar events have been consi-
dered to have been a result of more regional events caused by
recycling of isotopically light carbon from the
lower water column (e.g., McArthur et al. 2008).
However, that the Aalenian–Bajocian boundary
event is observed in both marine (Fig. 8) and
terrestrial settings (e.g., Hesselbo et al. 2003) has
been considered to be an indication that the
observed isotopic signals may have recorded
a global (rather than regional) perturbation of
the carbon cycle. As noted above, changes in
the export of neritic carbonate mud (e.g., Swart &
Eberli 2005) could also conceivably result in
a negative isotope excursion in the geological
record (e.g., Bodin et al. 2016; Ait-Itto et al.
2017). Hence a shift in the δ
13
C
micrite
signature is
possible without any relation to variations in
the global carbon isotope trend (Bodin et al. 2016,
2017). For this latter mechanism to be consi-
dered, sustained changes in the export of neritic
mud are required to reach the study site and affect
carbonate factories across Tethys. Furthermore,
the negative excursion occurring in both oceanic
and terrestrial reservoirs, provides an additional
challenge for this to be a viable mechanism.
In contrast to the Aalenian–Bajocian boundary
interval, more positive δ
13
C values (Fig. 8) in the
Early Bajocian Tethyan seaway could have been
linked to warmer climates and rising sea levels,
increased runoff and nutrient fluxes to the oceans, increasing
the fertility of surface waters (e.g., Sandoval et al. 2008;
Suchéras-Marx et al. 2012). For example Suchéras-Marx et al.
(2012) show that calcareous nannofossil fluxes increase mar-
kedly (mainly related to the rise of Watznaueria genus) from
the upper part of the Aalenian to the Early Bajocian, coinci-
ding with a positive shift in carbon isotope compositions of
bulk carbonate. High levels of CO
2
in the atmosphere could
have also accelerated the transfer of nutrients from the conti-
nents to the oceans, through increasing weathering. Indeed, as
noted above, significant injections of CO
2
have been asso-
ciated with major pulses of subduction-related magmatism,
linked to the opening of the Pacific Ocean and the breakup of
Pangaea (e.g., Bartolini & Larson 2001). Equally, the evolu-
tion of Tethyan seawater temperatures during the Middle
Jurassic period inferred from the oxygen isotopic composition
of belemnite rostra, bivalve shells and from fish teeth (see
Brigaud et al. 2009; Price 2010) reveal warmth during the
Early Bajocian and cooling from late Bajocian times through
into the Bathonian. Also, the oxygen isotope data of this study
(Fig. 7) broadly replicate this trend, whereby more negative
values are seen in the lower part of the succession and more
positive values are observed in the upper part of the section
and within the Bathonian. Such a pattern of warming and
cooling is consistent with an Early Bajocian transgression
noted above.
Increasing δ
13
C values in the Bajocian Tethyan seaway have
also been linked to elevated productivity, as shown by radio-
larian assemblages (Bartolini et al. 1999). O’Dogherty et al.
Fig. 6. Cross plot of δ
18
O and δ
13
C data from the Aalenian–Bajocian interval,
Óbánya valley, of the Mecsek Mountains, Hungary. Data from Raucsik (1997) is
also shown.
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(2006) further point out ammonite radiations during the Early
Bajocian, concomitant with increasing δ
13
C values. The Early
Bajocian positive excursion has also been correlated in the
southern margin of western Tethys with a “carbonate
production crisis” and concomitant with the onset of biosili-
ceous sedimentation in several basins (Bartolini et al. 1996).
The Komló Calcareous Marl Formation shows, however,
increasing carbonate content upwards (Velledits et al. 1986)
Fig. 7. Isotopic results (δ
13
C and δ
18
O
micrite
) from the Óbánya section. The ammonite data is from Velledits et al. (1986) and Galácz (1994).
Zonal boundaries are not possible to identify because of very scattered occurrences of diagnostic ammonites. Crosses are the data derived from
marls. The isotope curves (and 5 point running means) are plotted though the limestone data only.
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rather than any marked decreases in carbonate.
It is the Late Jurassic that sees biosiliceous
sedi mentation in the Óbánya valley (Velledits
et al. 1986).
Conclusions
Our study of the Komló Calcareous Marl
Formation of the Mecsek Mountains of
Hungary reveals a negative carbon isotope
excursion followed by positive values that
occurs near the base of the section (across the
Aalenian–Bajocian boundary). The origin of
this carbon-isotope anomaly is interpreted to lie
in significant changes to carbon fluxes stem-
ming from changes in primary production
linked to increasingly oligotrophic conditions,
caused for example, by reduced run off and
nutrient fluxes to the oceans, lowering the fer-
tility of surface waters which in turn leads to
lessened primary production and a negative δ
13
C
shift (e.g., O’Dogherty et al. 2006; Sandoval et
al. 2008). That the Aalenian–Bajocian boun-
dary carbon isotope event is observed in both
marine and terrestrial settings (e.g., Hesselbo et
al. 2003) indicates that the observed isotopic
signals record global (rather than regional) per-
turbation of the carbon cycle. Changes in the
export of neritic carbonate mud could also con-
ceivably result in a negative isotope excursion,
but this mechanism required sustained changes
affecting carbonate factories across Tethys.
Furthermore, the negative excursion occurring
in both oceanic and terrestrial reservoirs, chal-
lenges this as a viable mechanism. In view of
the gradual isotopic changes inferred from
these Tethyan carbonates, an explanation in
terms of the rapid dissociation of gas hydrates
also appears unlikely. This study of the Komló
Calcareous Marl Formation further confirms
that the carbon isotope curves of Bartolini et al.
(1999) and Sandoval et al. (2008), do indeed
serve as a global standard for Aalenian–
Bathonian δ
13
C variation.
Acknowledgments: This work has received
support from the SYNTHESYS Project
(http://www.synthesys.info/), financed by Euro-
pean Community Research Infrastructure
Action under the FP6 Structuring the European
Research Area Program. We thank Béla Raucsik
for assistance with fieldwork. The manu script
was considerably improved by constructive
reviews by Helmut Weissert and an anonymous
reviewer.
Fig. 8.
Carbon
isotope
stratigraphies of the
Aalenian–Bathonian interval from Óbánya compared with Southern Spain (from O'Dogherty et al. 2006), Cabo
Mondego, Portugal (from
Suchéras-Marx et
al. 2012); Chaudon Norante, SE France (from Suchéras-Marx et al. 2013);
W
adi Naqab, United
Arab Emirates (Hönig & John 2015) and the Umbria-Marche Basin, Italy(from Bartolini et al. 1999).
126
PRICE, FŐZY and GALÁCZ
GEOLOGICA CARPATHICA
, 2018, 69, 2, 117–127
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